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Authors

Vita Datsenko , 
Elina Khobotova *

Abstract

Background: Research in the field of sorption materials obtaining based on secondary resources is applicable, as it saves raw materials. One of the actively developing areas of chemical technology is the synthesis of ferrite composite materials (FC) as sorbents. Methods: The concentrations of Cu(II) and Zn(II) ions were determined by atomic absorption spectrometry. The FCs compositions was determined by X-ray phase analysis. The morphological features of FCs were studied by means of electron-probe microanalysis on a scanning electron microscope. The sorption activity of FCs was investigated in the processes of sorption of methyl violet by spectrophotometry. Results: The possibility of copper-zinc ferrite materials obtaining from sulfate copper-zinc electrolyte by the co-precipitation method in four modifications was substantiated and experimentally confirmed. The possibility of synthesized FCs using for water purification from organic dyes, such as methyl violet, was proven experimentally. The features and effectiveness of the FCs application as sorption materials were evaluated. Conclusions: The main stages of copper-zinc ferrite materials producing were determined. The producrion scheme of FCs obtaining was proposed. It was shown that the presence of ferrite phases in the form of spinel with the general formula FexZnyCuzO4 and the developed surface of the FCs determine their high sorption activity. Significance: The practical use of industrial wastewater as a man-made raw material for the technically useful materials production has been further developed.

Keywords:
copper-zinc ferrite materials; synthesis; co-precipitation; water purification; organic dyes; sorption characteristics

Article Details

References

[1]Larin, V., Datsenko, V., Egorova, L., Hraivoronskaia, I., & Herasymchuk, T. (2020). Physical and chemical properties of copper-zinc galvanic sludge in the process of thermal treatment. French-Ukrainian Journal of Chemistry, 8(1), 66–75. https://doi.org/10.17721/fujcV8I1P66-75

[2]Datsenko, V., Khimenko, N., Egorova, L., Svishchova, Y., Dubyna, O., Budvytska, O., Lyubymova, N., Pasternak, V., & Pusik, L. (2019). Construction of the algorithm for assessing the environmental safety of galvanic sludges. Eastern-European Journal of Enterprise Technologies, 6(10(102)), 42–48. https://doi.org/10.15587/1729-4061.2019.188251

[3]Datsenko, V. V., Khobotova, E. B., Vankevich, O. V., & Tolmachov, S. M. (2022). Technically useful properties of copper-zinc ferrites. Functional Materials, 29(1), 62–71. https://doi.org/10.15407/fm29.01.62

[4]Datsenko, V. (2021). Ion-exchange cleaning of oil washing water from chloride ions. Petroleum and Coal, 63(2), 467–474.

[5]Datsenko, V., & Larin, V. (2021). Evaluating the methods used for the regeneration process of copper-zinc solutions. Chemistry Journal of Moldova, 16(1), 88–98. https://doi.org/10.19261/cjm.2021.793

[6]Khobotova, E. B., Kaliuzhna, I. S., Datsenko, V. V., & Larin, V. I. (2021). Toxic and hydraulic activity of blast furnace slag as the main criteria for choosing the technology of their utilization. Journal of Chemistry and Technologies, 29(2), 312–320. https://doi.org/10.15421/jchemtech.v29i2.228352

[7]Khobotova, E., Hraivoronska, I., Kaliuzhna, I., & Ihnatenko, M. (2021). Sorption purification of wastewater from organic dyes using granulated blast-furnace slag. ChemChemTech, 64(6), 89–94. https://doi.org/10.6060/ivkkt.20216406.6302

[8]Datsenko, V. V., Khobotova, E. B., Belichenko, E. A., & Vankevich, O. V. (2021). Multifunctionality of composite material based on copper-zinc ferrite. Journal of Chemistry and Technologies, 29(4), 476–484. https://doi.org/10.15421/jchemtech.v29i4.240173

[9]Pashayan, A. A., & Karmanov, D. A. (2018). Recycling of electroplating wastes without formation of galvanic sludges. Ecology and Industry of Russia, 22(12), 19–21. https://doi.org/10.18412/1816-0395-2018-12-19-21

[10]Makarchuk, O., Dontsova, T., Perekos, A., Skoblik, A., & Svystunov, Y. (2017). Magnetic mineral nanocomposite sorbents for wastewater treatment. Journal of Nanomaterials, 2017, Article 8579598. https://doi.org/10.1155/2017/8579598

[11]Yang, Z., Li, Y., Zhang, X., Cui, X., He, S., Liang, H., & Ding, A. (2020). Sludge activated carbon-based CoFe₂O₄-SAC nanocomposites used as heterogeneous catalysts for degrading antibiotic norfloxacin through activating peroxymonosulfate. Chemical Engineering Journal, 384, Article 123319. https://doi.org/10.1016/j.cej.2019.123319

[12]Zhu, Z., Ma, C., Yu, K., Lu, Z., Liu, Z., Yan, Y., Tang, X., & Huo, P. (2020). Fabrication of CoFe₂O₄-modified and HNTs-supported g-C₃N₄ heterojunction photocatalysts for enhancing MBT degradation activity under visible light. Journal of Materials Science, 55, 4358–4371. https://doi.org/10.1007/s10853-019-04170-8

[13]Bagherzadeh, S. B., Kazemeini, M., & Mahmoodi, N. M. (2020). A study of the DR23 dye photocatalytic degradation utilizing a magnetic hybrid nanocomposite of MIL-53(Fe)/CoFe₂O₄: Facile synthesis and kinetic investigations. Journal of Molecular Liquids, 301, Article 112427. https://doi.org/10.1016/j.molliq.2019.112427

[14]Jafarinejad, S. (2017). Treatment of oily wastewater. In Petroleum waste treatment and pollution control (pp. 185–267). Elsevier. https://doi.org/10.1016/B978-0-12-809243-9.00006-7

[15]Zoria, O., Ternovtsev, O., Zoria, D., & Walery, M. (2019). Advanced resource-saving copper wastewater treatment by ferritization. Ways to Improve Construction Efficiency, 41, 148–162. https://doi.org/10.32347/2707-501X.2019.41.148-162

[16]Supong, K., Usapein, P., & Polburee, P. (2019). Analysis of environmental performances of ferritization method for the treatment of copper-ammonia wastewater under the optimized condition via RSM. Applied Environmental Research, 41(3), 42–56. https://doi.org/10.35762/AER.2019.41.3.4

[17]JCPDS–International Centre for Diffraction Data. (1994). Powder diffraction file (PDF-1), release 1994. International Centre for Diffraction Data.

[18]Rodriguez-Carvajal, J., & Roisnel, T. (1998). FullProf.98 and WinPLOTR: New Windows 95/NT applications for diffraction. Commission on Powder Diffraction Newsletter, (20).

[19]Patent UA 128532. Method for obtaining nanosized copper-zinc ferrites with superparamagnetic, catalyst and oxidant properties / V.V. Datsenko, E.B. Khobotova, V.I. Larin – 08.07.2024, Bull. N 32/2024.

[20]Patent UA 151030. Method for obtaining a ferrite composite material with sorbent and photocatalyst properties / V.V. Datsenko, E.B. Khobotova, O.I. Vankevich – 05.25.2022, Bull. N 21/2022.

[21]Patent UA 149385. Method for obtaining ferrites by purifying waste copper-zinc sulfate solutions / E.B. Khobotova, V.V. Datsenko, O.I. Vankevich – 11.10.2021, Bull. N 45/2021.

[22]Khobotova, E. B., Datsenko, V. V., & Larin, V. I. (2022). Method for synthesizing multi-metallic ferrite with sorption properties. Patent UA 151270, Bulletin No. 26/2022.